Introduction to Saponification
Saponification is a chemical reaction that involves the production of a metal salt or soap. The reaction involves the attack on a methyl ester, free fatty acid, triglyceride, or other glyceride by a hydroxide ion, –OH.
The hydroxide ion implies the presence of water in the system. If water could be eliminated, then there would be no soap formation. However, this is a practical impossibility. There is always some water present, and there will always be some soap formed when biodiesel is made.
The exception to this is when a solid (heterogeneous) catalyst is used which does not provide the free metal ions needed to form soap. These catalysts should provide biodiesel and glycerin that are free of soap. In reality, many of these supposed heterogeneous catalysts leach metals ions into the liquid and thus require some clean-up of the reaction products.
Soap must be removed from biodiesel after the reaction, and this can be done by either water washing, using a solid adsorbent mixed with the liquid, or by passing the liquid through a packed bed of ion exchange resin.
Soap is not formed when biodiesel is manufactured using a supercritical technology that does not require a catalyst. For more information on supercritical reactors, see Reactors for Biodiesel Production.
Additional Topics on Biodiesel Processing
Biodiesel Production Principles and Processes
Commercial and Large Scale Biodiesel Production Systems
Waste Management in Biodiesel Production
- Introduction to Farm Energy
- Introduction to Biodiesel
- Biodiesel Feedstocks
- Biodiesel Processing
- Biodiesel Utilization
- Biodiesel Online Library of Resources
Contributors to This Article
- Jon Van Gerpen, Professor, National Biodiesel Education Program, University of Idaho
- Joe Thompson, Research Support Scientist, Department of Biological and Agricultural Engineering, National Biodiesel Education Program, University of Idaho
- Joel Schumacher, Associate Specialist, Agricultural Economics, Montana State University